Michael J. Baldwin

Michael Baldwin is an Associate Professor of Chemistry at the University of Cincinnati. He is an inorganic chemist with research interests in catalysis, spectroscopy, bioinorganic chemistry, and oxygen activation. He received a BS degree in chemistry from Seattle University in 1986, and a PhD in chemistry from Stanford University in 1992 for work with Edward Solomon on spectroscopic studies of copper-peroxide complexes modeling the oxygen transport protein oxyhemocyanin and the enzyme oxytyrosinase. As a NIH postdoctoral fellow with Professor Vincent Pecoraro at the University of Michigan, he worked on models of the photosynthetic oxygen evolving complex. In 1997, he joined the faculty at the University of Cincinnati.

Ph.D.: Stanford University Palo Alto, CA, 1992 (Inorganic Chemistry)

B.S.: Seattle University Seattle, WA, 1986 (Chemistry)

• Bioinorganic Chemistry
• Catalysis
• Photochemistry
• Spectroscopy
• Oxygen Activation by Transition Metals

1998 University Research Council Faculty Research Support Grant Development of New Ligands that Support Nickel-dioxygen Reactions in Oxidation Catalysts $5,000

2005 University Research Council Faculty Research Support Grant Light-Triggered Metal Delivery by Bio-Inspired alpha-hydroxy Acid Ligands $6500

Grant: #NCE Investigators:Baldwin, Michael 01-01-2002 -08-31-2005 American Chemical Society - National Chapter Oxygen Activation by (Ni(II)) Polyoximate Complexes Role:PI $96,000.00

Grant: #ACS-PRF #33960-G3 Investigators:Baldwin, Michael 09-01-1999 -08-31-2001 American Chemical Society - National Chapter Oxygen Activiation by Nickel: Complexes of New Mixed Amide Oxime Ligands Role:PI $25,000.00 Closed Level:Private Non-Profit

Grant: #CHE-0955603 Investigators:Baldwin, Michael 04-15-2010 -03-31-2014 National Science Foundation Stimulus-Responsive Chelates for Light Triggered Release of Metals Role:PI $374,000.00 Completed

Peer Reviewed Publications

Clausen, H.; Levery, S.B.; Nudelman, E.; Baldwin, M.J.; Hakomori, S.-i. "Further Characterization of Type 2 and Type 3 Chain Blood Group A Glycosphingolipids from Human Erythrocyte Membranes". Biochemistry (1986), 25, 7075-7085.

Levery, S.B.; Nudelman, E.; Kannagi, R.; Symington, F. W.; Anderson, N. H.; Clausen, H.; Baldwin, M.J.; Hakomori, S.-i. "¹H-N.M.R. Analysis of Type-2 Chain Lacto-Gangliosides. Confirmation of Structure of a Novel Cancer-Associated Fucoganglioside, a-NeuAc-(2? 6)-ß-D-GlcpNAc-(1? 3)-Galp-(1? 4)-[a-L-Fucp-(1? 3)]-ß-D-Galp-(1? 4)-ß-D-Glcp-(1? 1)-Cer(VI⁶NeuAcIII³FucnLc₆Cer)". Carbohydr. Res. (1988), 178, 121-144.

Westmoreland, T. D.; Wilcox, D. E.; Baldwin, M.J.; Mims, W. B.; Solomon, E. I. "Detailed Spectroscopic Analysis of Half-Met Hemocyanins: Mixed Valent Contributions to Electronic Properties and Structure". J. Am. Chem. Soc. (1989), 111, 6106-6123.

Solomon, E. I.; Cole, J. L.; Baldwin, M.J. "Structure-Function Correlations in Copper Clusters in Proteins". Pure Appl. Chem. (1990), 62, 1063-1066.

Baldwin, M.J.; Ross, P. K.; Pate, J. E.; Tyeklar, Z.; Karlin, K. D.; Solomon, E. I. "Spectroscopic and Theoretical Studies of an End-on Peroxide-Bridged Coupled Binuclear Copper(II) Model Complex of Relevance to the Active Site in Hemocyanin and Tyrosinase". J. Am. Chem. Soc. (1991), 113, 8671-8679.

Thomann, H.; Bernardo, M.; Baldwin, M.J.; Lowery, M. D.; Solomon, E. I. "Pulsed ENDOR Study of the Native and High pH Perturbed Forms of the Blue Copper Site in Stellacyanin". J. Am. Chem. Soc. (1991), 113, 5911-5913.

Baldwin, M.J.; Root, D. E.; Pate, J. E.; Fujisawa, K.; Kitajima, N.; Solomon, E. I. "Spectroscopic Studies of a Side-on Peroxide-Bridged Binuclear Copper(II) Model Complex of Relevance to the Active Sites in Oxyhemocyanin and Oxytyrosinase". J. Am. Chem. Soc. (1992), 114, 10421-10431.

Solomon, E. I.; Baldwin, M.J.; Lowery, M. D. "Electronic Structure of Active Sites in Copper Proteins: Contributions to Reactivity". Chem. Rev. (1992), 92, 521-542.

Baldwin, M.J.; Gelasco, A.; Pecoraro, V. L. "The Effect of Protonation on [Mn(IV)(µ₂-O)]₂ Complexes". Photosynth. Res. (1993), 92, 303-308.

Baldwin, M.J.; Kampf, J. W.; Pecoraro, V. L. "The Linear Mn(II) Complex Mn₃(5-NO₂^-salimH)₂(Oac)₄ Provides an Alternative Structure Type for the Carboxylate Shift in Proteins". J. Chem. Soc., Chem. Commun. (1993), 1741-1743.

Pecoraro, V. L.; Baldwin, M.J.; Gelasco, A. "Interactions of Dioxygen and Its Reduced Derivatives with Manganese Coordination Complexes". Chem. Rev. (1994), 94, 807-826.

Baldwin, M.J.; Stemmler, T. L.; Riggs-Gelasco, P. J.; Kirk, M. L.; Penner-Hahn, J. E.; Pecoraro, V. L. "Structural and Magnetic Effects of Successive Protonations of Oxo Bridges in High Valent Manganese Dimers". J. Am. Chem. Soc. (1994), 116, 11349-11356.

Baldwin, M. J.; Kampf, J. W.; Kirk, M. L.; Pecoraro, V. L. "Structural and Magnetic Studies of Mn(II) Complexes of the Imidazole-Containing Ligand 5-NO₂-salimH [5-NO₂-salimH = 4-(2-(5-nitrosalicylideneamino)ethyl)imidazole] With Varying Nuclearity". Inorg. Chem. (1995), 34, 5252-5260.

Baldwin, M. J. ; Pecoraro, V. L. "Energetics of Proton-Coupled Electron Transfer in High-Valent Mn₂(µ-O)₂ Systems: Models of Water Oxidation by the Oxygen Evolving Complex". J. Am. Chem. Soc. (1996), 118, 11325-11326.

Stemmler, A. J.; Barwinski, A.; Baldwin, M. J.; Young, V. G, Jr.; Pecoraro, V. L. "Facile Preparation of Face Differentiated, Chiral 15-Metallacrown-5 Complexes". J. Am. Chem. Soc. (1996), 118, 11962-11963.

Pecoraro, V. L.; Baldwin, M. J.; Caudle, M. T.; Hsieh, W.-Y.; Law, N. A. "A Proposal for Water Oxidation in Photosystem II". Pure Appl. (1998), 70, 925-929.

Baldwin, M. J.; Law, N. A.; Stemmler, T. L.; Penner-Hahn, J. E.; Pecoraro, V. L. "Reactivity of [Mn_IV(salpn)]₂(µ-O, µ-OCH₃)+ and [Mn^IV(salpn)]₂(µ-O, µ-OH)⁺: Effects of Proton Lability and Hydrogen Bonding". Inorg. Chem. (1999), 38, 4801-4809.

Baldwin, M. J.; Krause Bauer, J. A. "cis-Bis(Ethylenediamine)-Bis(Pyridyl)Nickel(II) Nitrate". Acta Cryst. (1999), C55, 1772-1773.

Goldcamp, M. J.; Rosa, D. T.; Landers, N. A.; Mandel, S. M.; Krause Bauer, J. A.; Baldwin, M. J. "Facile and Versatile Synthesis of Polydentate Metal Chelators with Both Amide and Oxime Donor Groups". Synthesis (2000), 2033-2038.

Goldcamp, M.J.; Krause Bauer, J.A.; Baldwin, M.J. "Tris[2-(benzoylamino)ethyl]amine". Acta Cryst. (2000), C56, e602-e603.

Rosa, D. T.; Krause Bauer, J.A.; Baldwin, M. J. "Structural and Spectroscopic Studies of the Versatile Coordination Chemistry of the Chiral Ligand N,N-bis(1-propan-2-onyl oxime)methionine N’-methylamide with Ni^II and Zn^II". Inorg. Chem. (2001), 40, 1606-1613.

Yanes, E.G.; Gratz, S.R.; Baldwin, M.J.; Robison, S.E.; Stalcup, A.M. "Capillary Electrophoretic Application of 1-Alkyl-3-methylimidazolium-based Ionic Liquids". Anal. Chem. (2001), 73, 3838-3844.

Goldcamp, M.J.; Robison, S.E.; Krause Bauer, J.A.; Baldwin, M.J. "Oxygen Reactivity of a Ni(II)-Polyoximate Complex". Inorg. Chem. (2002), 41, 2307-2309.

Goldcamp, M.J.; Krause Bauer, J.A.; Baldwin, M.J. "Tris(1-propan-2-only oxime)amine". Acta Cryst. (2002), E58, o1354-o1355.

Goldcamp, M.J.; Robison, S.E.; Squires, L.N.; Rosa, D.T.; Vowels, N.K.; Coker, N.; Krause Bauer, J.A.; Baldwin, M.J. "Structural and Spectroscopic Studies of Ni(II) complexes with a Library of Bis(oxime)amine-Containing Ligands". Inorg. Chem. (2003), 42, 717-728.

Baldwin, M.J. "A Literature-Based, One-Quarter Inorganic Chemistry laboratory Course". J. Chem. Ed. (2003), 80, 307-310.

Baldwin, M.J. "Oxygen activation by nickel complexes: Development of oxygen-active Ni(II)-oximate complexes". ChemTracts – Inorganic Chemistry (2003), 16, 1-14.

Jones, R.M.; Baldwin, M.J. "Development of a theoretical model of a Nickel(II) tris(oxime)amine dichloride complex with calibration by x-ray crystallography and vibrational spectroscopy". J. Phys. Chem. A. (2004), 108, 3537-3544.

Edison, S.E.; Hotz, R.P.; Baldwin, M.J. "Aerobic Oxidation of Methanol by a Ni(II)-O2 Reaction". Chem. Commun. (2004), 1212-1213.

Zhuang, J.; Amaroso, J.H.; Kinloch, R.; Dawson, J.H.; Baldwin, M.J.; Gibney, B.R. "Design of a five-coordinate heme protein maquette: A spectroscopic model of deoxymyoglobin". Inorg. Chem. (2004), 43, 8218-8220.

Edison, S.E.; Krause Bauer, J.A.; Baldwin, M.J. "Aqua(pyridine N-oxide- ?O[tris(2-hydroxyaminopropyl) amine-?⁴N]nickel(II) dinitrate". Acta Cryst. (2004), E60, m1930-m1932.

Krause Bauer, J.A.; Edison, S.E.; Baldwin, M.J. "Bis(ethylenediamine)nickel(II) dinitrate". Acta Cryst. (2005), E61, m82-m84.

Goldcamp, M.J.; Krause-Bauer, J.A.; Baldwin, M.J. "Zn(TRISOX)(OAc)₂". J. Chem. Crytallog. (2005), 35, 77-83.

Deters, E.A.; Goldcamp, M.J.; Krause Bauer, J.A.; Baldwin, M.J. "Anion-controlled nuclearity in nickel complexes with potentially dinucleating, poly(oxime)amine ligands". Inorg. Chem. (2005), 44, 5222-5228.

Cheruzel, L.E.; Edison, S.E.; Cecil, M.R.; Mashuta, M.S.; Baldwin, M.J.; Buchanan, R.M. "Structural and spectroscopic characterization of a copper(II) complexes of a new bis-amide functionalized imidazole tripod and evidence for the formation of a mononuclear end-on Cu-OOH species". Inorg. Chem. 2006, 45, 3191-3202.

Zhuang, J.; Amoroso, J.H.; Kinloch, R.; Dawson, J.H.; Baldwin, M.J.; Gibney, B.R. "Evaluation of electron-withdrawing group effects on heme binding in a designed protein: Implications for heme a in cytachrome c oxidase". Inorg. Chem. 2006, 45, 4685-4694.

Jones, R.M.; Goldcamp, M.J.; Krause, J.A.; Baldwin, M.J. "Theoretical, structural, and spectroscopic studies of a series of NiII(TRISOXH3)X2 complexes". Polyhedron 2006, 25, 3145-3158.

S.E. Edison, S.D. Conklin, N. Kaval, L.E. Cheruzel, J.A. Krause, C.J. Seliskar, W.R. Heineman, R.M. Buchanan, M.J. Baldwin. "Spectroscopic characterization of a Ni-organic radical intermediate in the aerobic oxidation of methanol catalyzed by a Ni(II)(polyoximate) complex". Inorganica Chimica Acta 2008, 361, 947-955.

H. Sayre, K. Milos, M.J. Goldcamp, C.A. Schroll, J.A. Krause, M.J. Baldwin, "Mixed-donor, alpha-hydroxy acid-containing chelates for binding and light-triggered release of iron", Inorg. Chem., 2010, 49, 4433-4439.

J.E. Grabo, M.A. Chrisman, L.M. Webb, M.J. Baldwin, “Photochemical reactivity of the Fe(III) complex of a mixed-donor, alpha-hydroxy acid-containing chelate and its biological relevance to photoactive marine siderophores,” Inorg. Chem., 2014, 53, 5781-5787.

M. A. Chrisman, R.R. Baum, J. E. Grabo, J. A. Krause, D. L. Tierney, M. J. Baldwin, “Structure, spectroscopy, stability, and bridge exchange in the M3O4 incomplete-cubane complexes, [MIII3(Sal-AHA)3(µ-OR)]- (M = Fe, Ga),” Polyhedron, 2015, 100, 164-169.

M.J. Goldcamp, D.M. Goldcamp, K. Slack, M.J. Baldwin, "Effect of the Denticity of Tripodal Amine Ligands Containing Multiple Oximate Donors on the Catecholase Activity of Their Nickel(II) Complexes."  Inorg. Chem. Comm.  2015, 63, 53-56.

J. E. Grabo, S. M. Trotta, M. J. Baldwin, "Major changes in structure and photochemistry of Fe(III) complexes due to minor changes in their salicylidene/alpha-hydroxy acid-containing chelates", Inorg. Chem. Commun., 2017, 84c, 204-206.

J.E. Vernia, M.R. Warmin, J. A. Krause, D.L. Tierney, M.J. Baldwin, “Photochemistry and anion-controlled structure of Fe(III) Complexes with an alpha-hydroxy acid-containing tripodal amine chelate”, Inorg. Chem., 2017, 56, 13029-13034.

M. A. Chrisman, J. A. Krause, M. J. Baldwin, “Photochemistry of Uranyl Complexes with the Salicylidene-alpha-Hydroxy Acid Chelates, X-Sal-AHA-Sal-AHA,” Polyhedron, 2017, 141, 271-275.

G.K. Weragoda, N.M. Abdelaziz, D. Govorov, R. Merugu, L.J. Patton, J.E. Grabo, R.A.A.U. Ranaweera, A.C. Ratliff, W.D. Mendis, N. Ahmed, K.H. Vilinsky, M. Abe, M.J. Baldwin, and A.D. Gudmundsdottir, “Excited-State Intramolecular Proton Transfer in Salicylidene-α-Hydroxy Carboxylate Derivatives: Direct Detection of the Triplet Excited State of the cis-Keto Tautomer”, J. Phys. Chem. A,  2023, 127, 2765-2778. DOI: 10.1021/acs.jpca.3c00543

M.R. Warmin, D.J. DuPonty, N.S. Poland, M.A. Chrisman, J.A. Krause, M.J. Baldwin, “Structure, spectroscopy, and metal exchange among M(III) clusters with salicylidene-a-hydroxy acid chelaes (M = Al, Ga, In, Fe)”, Polyhedron, 2023, 224, 116592

Book Chapter

Solomon, E. I.; Baldwin, M.; Ross, P. K.; Tuczek, F. "Electronic-Structural Correlations of Dioxygen Binding and Activation by Binuclear Copper and Cobalt Complexes". In Dioxygen Activation and Homogeneous Catalytic Oxidation; L. I. Simandi, Ed(s); Elsevier: Amsterdam, (1991), pp 357-366.

Pecoraro, V. L.; Gelasco, A.; Baldwin, M. "A Modelling Approach for Understanding the Reactivity and Mechanism of Manganese Enzymes". In Mechanistic Bioinorganic Chemistry, Advances in Chemistry Series; H. H. Thorp and V. L. Pecoraro, Ed(s); ACS Books: New York, (1995), pp 265-301.

Pecoraro, V. L.; Gelasco, A.; Baldwin, M. "Modelling the Chemistry and Properties of Multinuclear Manganese Enzymes". In Bioinorganic Chemistry: An Inorganic Perspective of Life, NATO/ ASI Series; D. P. Kessissoglou, Ed(s); Klewer Academic Publishers: Dordrecht, The Netherlands, (1995), pp 287-298.

Pecoraro, V. L.; Baldwin, M. J.; Caudle, M. T.; Law, N. A.; Kampf, J. W.; Rasmussen, P. G. "A Modelling Approach to Understanding Water Oxidation in Photosynthesis". In Photosynthesis: from Light to Biosphere; P. Mathis, Ed(s); Klewer Academic Publishers: Dordrecht, The Netherlands, (1995), pp 377-380.

M.J. Baldwin, J.A. Krause, M.J. Goldcamp, M. Haven, S.E. Edison, L.N. Squires. "Bioinspired aerobic substrate oxidation: A Ni(II)-oximate catalyst that parallels biological alcohol and amine oxidation chemistry". In Bioinorganic Chemistry: Cellular Systems and Synthetic Models ; Eric C. Long and Michael J. Baldwin, Ed(s); American Chemical Society: Washington, D.C., (2009), pp 133-150.

Book

Eric C. Long and Michael J. Baldwin, Eds. Bioinorganic Chemistry: Cellular Systems and Synthetic Models; American Chemical Society: Washington, D.C., 2009.

Peer Reviewed Publications

Sayre, Hannah; Milos, Kyle; Goldcamp, Michael J; Schroll, Cynthia A; Krause, Jeanette A; Baldwin, Michael J (2010. ) Mixed-donor, alpha-hydroxy acid-containing chelates for binding and light-triggered release of iron.Inorganic chemistry, , 49 (10 ) ,4433-9 More Information

Zhuang, Jinyou; Amoroso, Jennifer H; Kinloch, Ryan; Dawson, John H; Baldwin, Michael J; Gibney, Brian R (2006. ) Evaluation of electron-withdrawing group effects on heme binding in designed proteins: implications for heme a in cytochrome c oxidase.Inorganic chemistry, , 45 (12 ) ,4685-94 More Information

Cheruzel, Lionel E; Cecil, Matthew R; Edison, Sara E; Mashuta, Mark S; Baldwin, Michael J; Buchanan, Robert M (2006. ) Structural and spectroscopic characterization of copper(II) complexes of a new bisamide functionalized imidazole tripod and evidence for the formation of a mononuclear end-on Cu-OOH species.Inorganic chemistry, , 45 (8 ) ,3191-202 More Information

Deters, Elizabeth A; Goldcamp, Michael J; Krause Bauer, Jeanette A; Baldwin, Michael J (2005. ) Anion-controlled nuclearity in nickel complexes with potentially dinucleating, poly(oxime) amine ligands.Inorganic chemistry, , 44 (15 ) ,5222-8 More Information

Zhuang, Jinyou; Amoroso, Jennifer H; Kinloch, Ryan; Dawson, John H; Baldwin, Michael J; Gibney, Brian R (2004. ) Design of a five-coordinate heme protein maquette: a spectroscopic model of deoxymyoglobin.Inorganic chemistry, , 43 (26 ) ,8218-20 More Information

Goldcamp, Michael J; Edison, Sara E; Squires, Leah N; Rosa, Dell T; Vowels, Neil K; Coker, Nathan L; Krause Bauer, Jeanette A; Baldwin, Michael J (2003. ) Structural and spectroscopic studies of nickel(II) complexes with a library of Bis(oxime)amine-containing ligands.Inorganic chemistry, , 42 (3 ) ,717-28 More Information

Goldcamp, Michael J; Robison, Sara E; Krause Bauer, Jeanette A; Baldwin, Michael J (2002. ) Oxygen reactivity of a nickel(II)-polyoximate complex. Inorganic chemistry, , 41 (9 ) ,2307-9

Yanes, E G; Gratz, S R; Baldwin, M J; Robison, S E; Stalcup, A M (2001. ) Capillary electrophoretic application of 1-alkyl-3-methylimidazolium-based ionic liquids. Analytical chemistry, , 73 (16 ) ,3838-44

Rosa, D T; Krause Bauer, J A; Baldwin, M J (2001. ) Structural and spectroscopic studies of the versatile coordination chemistry of the chiral ligand N,N-bis(1-propan-2-onyl oxime)-L-methionine N'-methylamide with Ni(II) and Zn(II). Inorganic chemistry, , 40 (7 ) ,1606-13

Baldwin, Michael J.; Law, Neil A.; Stemmler, Timothy L.; Kampf, Jeff W.; Penner-Hahn, James E.; Pecoraro, Vincent L. (1999. ) Reactivity of [{Mn(IV)(salpn)}(2)(&mgr;-O,&mgr;-OCH(3))](+) and [{Mn(IV)(salpn)}(2)(&mgr;-O,&mgr;-OH)](+): Effects of Proton Lability and Hydrogen Bonding. Inorganic chemistry, , 38 (21 ) ,4801-4809

Invited Presentations

(03-09-2000. ) Kent State University, Kent, OH.

(10-09-2000. ) Eastern Michigan University, Ypsilanti, MI.

(02-02-2001. ) Wright State University, Dayton, OH.

(03-08-2001. ) College of Mount St. Joseph, Cincinnati, OH.

(03-23-2001. ) Indiana University of Pennsylvania, Indiana, PA.

(04-06-2001. ) University of Evansville, Evansville, IN.

(10-30-2001. ) University of Michigan, Ann Arbor, MI.

(01-11-2002. ) University of Kentucky, Lexington, KY.

(01-30-2002. ) The Ohio State University, Columbus, OH.

(02-14-2002. ) Miami University, Oxford, OH.

(03-04-2002. ) University of California, Santa Cruz, Santa Cruz, CA.

(03-05-2002. ) Stanford University, Palo Alto, CA.

(03-07-2002. ) University of California, Davis, Davis, CA.

(04-23-2002. ) University of Arizon, Tucson, AZ.

(04-25-2002. ) Arizona State University, Tempe, AZ.

(04-26-2002. ) University of New Mexico, Albuquerque, NM.

(09-03-2002. ) Purdue University, West Lafayette, IN.

(09-04-2002. ) I.U.P.U.I, Indianapolis, IN.

(11-07-2002. ) Indiana University, Bloomington, IN.

(03-14-2003. ) University of Louisville, Louisville, KY.

(03-24-2003. ) Murray State University, Murray, KY.

(11-07-2003. ) College of St. Mary, South Bend, IN.

(11-18-2003. ) College of Mt. St. Joseph, Cincinnati, OH.

(01-30-2004. ) Xavier University, Cincinnati, OH.

(03-19-2004. ) Illinois State University, Normal, IL.

(10-26-2005. ) Austin Peay State University, Clarksville, TN.

(04-10-2006. ) Michigan State University, East Lansing, MI.

(06-07-2006. ) New Suderophore-inspired Agents for Tight Binding and Light-triggered Release of Iron .NSF Inorganic Chemistry Workshop, Blaine, WA.

(11-01-2006. ) Butler University, Indianapolis, IN.

(03-23-2007. ) Shippensburg University, Shippensburg, PA.

(10-24-2007. ) Delaware Valley College, Doylestown, PA.

(11-06-2007. ) College of Mt. St. Joseph, Cincinnati, OH.

(06-12-2008. ) Aerobic Oxidation of Alcohols and Amines by a Nickel-Organic Redox Hybrid .American Chemical Society Central Regional Meeting, Columbus, OH. Professional Meeting. .

(04-07-2009. ) Indiana State University, Terre Haute, IN. Other Institution. .

(04-24-2009. ) Duquesne University, Pittsburgh, PA. Other Institution. .

(10-23-2009. ) Eastern Kentucky University, Richmond, KY. Other Institution. .

(11-03-2009. ) College of Mount St. Joseph, Cincinnati, OH. Other Institution. .

Michael J. Baldwin (04-29-2011. ) Bioinspired Inorganic Chemistry: Catalysis and Metal Availability .Ohio State University.

Michael J. Baldwin (03-25-2011. ) Bioinspired Inorganic Chemistry: Catalysis and Metal Availability .Austin Peay State University.

Michael J. Baldwin (11-01-2011. ) Bioinspired Inorganic Chemistry: Catalysis and Metal Availability .College of Mount St. Joseph, Cincinnati, OH.

Michael J. Baldwin (03-28-2012. ) Bio-inspired Inorganic Chemistry: Controlling Metal Availability and Catalyzing Aerobic Oxidations .Worcester Polytechnic Institute, Worcester, MA. Other Institution. .

Michael J. Baldwin (03-29-2012. ) Bio-inspired Inorgamic Chemistry: Controlling Metal Availability and Catalyzing Aerobic Oxidations .University of Massachusetts, Amherst, MA. Other Institution. .

Michael J. Baldwin (10-11-2012. ) Bio-inspired Inorgamic Chemistry: Controlling Metal Availability and Catalyzing Aerobic Oxidations .Kent State University, Kent, OH. Other Institution. .

Michael J. Baldwin (11-05-2013. ) Bio-inspired Inorganic Chemistry: .College of Mount St. Joseph. Other Institution. .

Michael J. Baldwin (02-07-2014. ) Invited Seminar .University of Dayton Chemistry Department, Dayton, OH. Other Institution. . Level:State

Michael J. Baldwin (03-13-2016. ) Bioinspired, alpha-Hydroxy Acid-containing Chelates for Tight-binding and Light-triggered Release of Metals .251st American Chemical Society National Meeting, San Diego, CA. Level:National

Michael J. Baldwin (05-18-2016. ) Bioinspired chelates for light-responsive control of transition metal availability .ACS Central Regional Meeting, Covington, KY. Level:Regional

Michael J. Baldwin (06-09-2011. ) Biologically-inspired alpha-hydroxy acid-containing chelates for light-responsive, reductive release of iron .ACS Central Regional Meeting, Indianapolis, IN.

Michael J. Baldwin (05-22-2007. ) Agents for tight binding and light-triggered release of iron .ACS Central Regional Meeting, Covington, KY.

Michael J. Baldwin (05-17-2000. ) Complexes of mixed amide/oxime ligands: Models for ligand contributions to redox chemistry in metalloenzymes .ACS Central Regional Meeting, Covington, KY.

Michael J. Baldwin (10-21-2016. ) Bioinspired, alpha-hydroxy acid-containing chelates for tight binding and light-triggered release of metals .Marshall University, Huntington, WV.

Michael Baldwin (10-20-2017. ) Invited Seminar .Xavier University, Cincinnati, OH. Other Institution. .

Michael Baldwin (11-02-2017. ) Invited Seminar .DePauw University, Greencastle, IN. Other Institution. .

Michael Baldwin (11-07-2017. ) Invited Seminar .University of Akron, Akron, OH. Other Institution. .

Michael Baldwin (02-26-2021. ) Bio-inspired Inorganic Chemistry: Taking Control of Transition Metal Chemistry .Marshall University, Delivered Online. Other Institution. .

Michael Baldwin (03-26-2021. ) Bio-inspired Inorganic Chemistry: Two examples from the Baldwin Lab .Mount Saint Joseph University, Delivered Online. Other Institution. .

Poster Presentations

(01-1998. ) Progress on Oxygen Activation by Nickel Complexes .Metals in Biology Gordon Research Conference, Ventura, CA. .

(08-1998. ) In pursuit of oxygen activation with two-electron chemistry by mono- and dinuclear nickel complexes .– 216th American Chemical Society National Meeting, Boston, MA. .

(07-1999. ) Toward productive oxygen activation by Ni(II) complexes .9th International Conference on Biological Inorganic Chemistry, Minneapolis, MN. .

(01-2001. ) Structural diversity and oxygen reactivity of nickel complexes with oxime-containing ligands .Metals in Biology Gordon Research Conference, Ventura, CA. .

(01-2002. ) Control of electron stoichiometry in reactions of Ni(II) with O₂ .Metals in Biology Gordon Research Conference, Ventura, CA. .

(02-2003. ) Reactivity studies of oxygen-active Ni(II)-oximate complexes .Metals in Biology Gordon Research Conference, Ventura, CA. .

(01-2004. ) Aerobic oxidation of alcohol and amine substrates by reaction of O₂ with a Ni(II)poly(oximate) complex .Metals in Biology Gordon Research Conference, Ventura, CA. .

(01-2005. ) Characterization of a Ni(II)-organic redox hybrid that promotes aerobic oxidation of alcohol and amine substrates .Metals in Biology Gordon Research Conference, Ventura, CA. .

(01-2006. ) Siderophore-Inspired Metal Storage/Transport Agents with Light-Triggered Release .Metals in Biology Gordon Research Conference, Ventura, CA. .

H. Sayre, C. Schroll, J.A. Krause, M.J. Baldwin (10-24-2008. ) New alpha-hydroxy Acid-Containing Ligands for Tight Binding and Light-Triggered Release of Iron .Oesper Symposium, UC. .

Michael Baldwin (01-31-2010. ) New alpha-hydroxy acid-containing ligands for tight binding and light-triggered release of iron .Metals in Biology Gordon Research Conference, Ventura, CA. . Level:International

Mark Shelton (03-05-2010. ) Modification of ancillary functional groups in a light-responsive complex .UC Graduate Poster Forum, University of Cincinnati. . Level:University

Mark Shelton (10-08-2010. ) Novel light responsive iron chelates .Oesper symposium, UC. . Level:Local

Jessica Veite, Michael Goldcamp (10-08-2010. ) Asymmetric di-imino ligands containing alpha-hydroxy acid group for photo-initiated iron release .Oesper symposium, UC. . Level:Local

Michael J. Baldwin*, Mark A. Shelton, Jennifer E. Grabo, Suzanne M. Junker, Zachary Lambert, Hannah Sayre, Jeanette A. Krause, Jessica Viete, Michael J. Goldcamp, Jennifer Meyer, Richard P. Hotz (02-01-2011. ) New alpha-hydroxy acid-containing chelates for light-responsive, reductive release of iron .Metals in Biology Gordon Research Conference, Ventura, CA. . Conference. .

Mark Shelton, Michael J. Baldwin (10-14-2011. ) Novel Light Responsive alpha-Hydroxy Acid Iron Chelates .Oesper Symposium, Cincinnati, OH. . UC. .

Mark Shelton (10-28-2011. ) Novel Light Responsive alpha-Hydroxy Acid Iron Chelates .Ohio Inorganic Weekend, Cincinnati, OH. . UC. .

Jennifer Grabo (10-28-2011. ) Photochemistry of Iron Complexes of alpha-Hydroxy Acid Derivatives .Ohio Inorganic Weekend, Cincinnati, OH. . UC. .

Jennifer Grabo, Michael J. Baldwin (10-14-2011. ) Photochemistry of Iron Complexes of alpha-Hydroxy Acid Derivatives .Oesper Symposium, Cincinnati, OH. . UC. .

Gleason Wilson, Michael J. Baldwin (10-14-2011. ) Metal-Iminoxyl Complex Activates Oxygen .Oesper Symposium, Cincinnati, OH. . UC. .

Gleason Wilson (10-28-2011. ) Metal-Iminoxyl Complex Activates Oxygen .Ohio Inorganic Weekend, Cincinnati, OH. . UC. .

Michael J. Baldwin (01-22-2012. ) Tuning Bio-inspired alpha-Hydroxy Acid-containing Chelates for tight binding and light-responsive release of iron .Metals in Biology Gordon Research Conference, Ventura, CA. . Conference. .

Jennifer Vernia, Matthew Gross, Richard P. Hotz, Michael J. Baldwin (10-12-2012. ) Synthesis of Iron Complexes Containing an α-Hydroxy Acid Functional Group .Oesper Symposium, Cincinnati, OH. .

Mark A. Shelton, Hannah Sayre, Jeanette A. Krause, Michael J. Goldcamp, Michael J. Baldwin (03-01-2012. ) Novel light responsive α-hydroxy acid iron chelates .UC Graduate Poster Forum, Cincinnati, OH. .

Mark A. Shelton, Hannah Sayre, Jeanette A. Krause, Michael J. Goldchamp, Michael J. Baldwin (03-25-2012. ) Novel light responsive α-hydroxy acid iron chelates .American Chemical Society National Meeting, San Diego, CA. .

Mark A. Shelton, Michael J. Goldcamp, Michael J. Baldwin (10-12-2012. ) Modification of Light Responsive α-hydroxy acid Iron Chelates .Oesper Symposium, Cincinnati, OH. .

Jennifer Grabo, Mark Shelton, Lindsay Webb, Michael J. Baldwin (10-12-2012. ) Photochemistry of iron complexes of alpha-hydroxy acid derivatives .Oesper Symposium, Cincinnati, OH. .

Jennifer Grabo, Mark Shelton, Mark Chrisman, Jennifer Vernia, Lindsay Webb, Michael J. Baldwin (03-01-2012. ) Photochemistry of iron complexes of alpha-hydroxy acid derivatives .UC Graduate Poster Forum, Cincinnati, OH. .

Mark Chrisman, Austin Hayes, Michael J. Baldwin (10-12-2012. ) Formation of transition metal complexes using alpha-hydroxy acid containing chelates .Oesper Symposium, Cincinnati, OH. .

Michael J. Baldwin, Jennifer Grabo, Mark Chrisman (01-20-2013. ) Bio-inspired alpha-Hydroxy Acid-containing Chelates for Tight Binding and Light-responsive Release of Transition Metals .Metals in Biology Gordon Research Conference, Ventura, CA. .

Jennifer Grabo, Lindsay Webb, Michael J. Baldwin (09-08-2013. ) Reactivity of photoactive iron complexes .ACS National Meeting, Indianapolis, IN. . Level:National

Mark Chrisman, Michael J. Baldwin (09-08-2013. ) Metal complexes containing α-hydroxy acid chelating ligands .ACS National Meeting, Indianapolis, IN. . Level:National

Jennifer Vernia (09-08-2013. ) New α-hydroxy acid-containing Tripodal Amine Chelates and their Iron Complexes .ACS National Meeting, Indianapolis, IN. . Level:National

Mark Chrisman (10-25-2013. ) The formation of α-hydroxy acid containing metal complexes .Oesper Symposium?ACS Local Section Mtg, University of Cincinnati. . Level:Local

Jennifer Grabo, Lindsay Webb, Michael J. Baldwin (10-25-2013. ) Photochemistry of complexes containing α-hydroxy acid chelates .Oesper Symposium/ACS local section mtg, University of Cincinnati. . Level:Local

Jennifer Vernia (10-25-2013. ) Bioinspired α-hydroxy acid-containing Tripodal Amine Chelates and their Metal Complexes .Oesper Symposium/ACS local section meeting, University of Cincinnati. . Level:Local

Jennifer Vernia, Michael J. Baldwin (11-15-2013. ) Bioinspired α-hydroxy acid-containing Tripodal Amine Chelates and their Metal Complexes .Ohio Inorganic Weekend, University of Dayton, Dayton, OH. . Level:Regional

Jennifer Grabo, Michael J. Baldwin (11-15-2013. ) Photochemistry of complexes containing α-hydroxy acid chelates .Ohio Inorganic Weekend, University of Dayton, Dayton, OH. . Level:Regional

Mark Chrisman, Michael J. Baldwin (11-15-2013. ) The formation of α-hydroxy acid containing metal complexes .Ohio Inorganic Weekend, University of Dayton, Dayton, OH. . Level:Regional

Michael J. Baldwin, Jennifer E. Grabo, Mark A. Chrisman, Jeanette A. Krause (01-26-2014. ) Reactivity of Fe(III) Complexes of Mixed-donor, alpha-hydroxy Acid Chelates and their Implications for Photoactive Siderophores .Metals in Biology Gordon Research Conference, Ventura, CA. . Conference. . Level:International

Jennifer E. Grabo, Michael J. Baldwin (10-24-2014. ) Effect of Small Chelate Changes on the Formation and Photoactivity of Complexes .Oesper Symposium/ACS Local Section Meeting, University of Cincinnati. . Level:Local

Mark A. Chrisman, Jeanette A. Krause, Michael J. Baldwin (10-24-2014. ) Complexes containing α-hydroxy acid chelates .Oesper Symposium/ACS Cincinnati Section Meeting, University of Cincinnati. . Level:Local

Jennifer E. Vernia, Michael J. Baldwin (08-12-2014. ) Bioinispired α-hydroxy acid-containing Tripodal Amine Chelates and their Metal Complexes .ACS National Meeting, San Francisco, CA. . Level:National

Jennifer E. Vernia, Michael J. Baldwin (10-24-2014. ) Bioinspired α-hydroxy acid-containing Tripodal Amine Chelates and their Metal Complexes .Oesper Symposium/ACS Cincinnati Section Meeting, University of Cincinnati. . Level:Local

Michael J. Baldwin (01-25-2015. ) Molecular Architectures and Photochemistry Facilitated by the alpha-Hydroxy Acid Group in Mixed-Donor Chelates .Metals in Biology Gordon Research Conference, Ventura, CA. . Conference. . Level:International

Jennifer Vernia, Michael Baldwin (08-15-2015. ) Bioinspired α-hydroxy Acid Containing Tripodal Amine Chelates and Photoactivity of their Metal Complexes .250th ACS National Meeting, Boston, MA. . Conference. . Level:National

Jennifer Vernia, Michael Baldwin (11-13-2015. ) Bioinispired α-hydroxy acid-containing Tripodal Amine Chelates, New Derivatives and their Metal Complexes .Oesper Symposium, Cincinnati, OH. . Level:Local

Mark Chrisman, Michael Baldwin (11-13-2015. ) Photoactive uranyl complexes of salicylidene-α-hydroxy acid chelates .Oesper Symposium, Cinainnati, OH. . Level:Local

Ahmed Elshewy, Michael Baldwin (11-13-2015. ) Formation of new transition metal complexes containing two α-hydroxy acid moities .Oespere Symposium, Cincinnati, OH. . Level:Local

Michael J. Baldwin, et al. (01-25-2016. ) Structure and Photochemistry of Metal Complexes with Mixed-donor Chelates Containing alpha-Hydroxy Acids .Metals in Biology Gordon Research Conference, Ventura, CA. . Level:International

Mark Chrisman, Michael Baldwin (05-19-2016. ) Complexes containing α-hydroxy acid chelating ligands .Central Region ACS Meeting, Covington, KY. .

Jennifer Vernia, Michael Baldwin (05-20-2016. ) Bioinispired α-hydroxy acid-containing tripodal amine chelates: New derivatives and their metal complexes .Central Regional ACS Meeting, Covington, KY. .

Ahmed Elshewey, Michael Baldwin (05-20-2016. ) Formation of new transition metal complexes containing two α-hydroxy acid moities .Centerl Region ACS Meeting, Covington, KY. .

Alena Moore, Aubrey Malott, Aleksander Thomas, Michael J. Goldcamp, Michael J. Baldwin (10-28-2016. ) New tripodal ligands with alpha-hydroxy acid groups and their photoreactivity .Oesper symposium, University of Cincinnati. .

Mark Chrisman, Michael Baldwin (10-28-2016. ) Photoactive Uranyl Complexes of α-Hydroxy Acid Chelates .Oesper Symposium, University of Cincinnati. .

Ahmed Elshewy, Michael Baldwin (10-28-2016. ) New transition metal complexes containing two alpha hydroxy acid moieties .Oesper Symposium, University of Cincinnati. .

Jennifer Vernia, Michael Baldwin (10-28-2016. ) Bioinspired Tripodal Amine Chelates Containing α-hydroxy Acids and α-hydroxy Amides and Photochemistry of their Metal Complexes .Oesper Symposium, University of Cincinnati. .

Michael Baldwin (01-22-2017. ) Control of Metal-Metal Interactions and Photochemistry in Fe(III) Complexes of Chelates Containing alpha-Hydroxy Acids .Metals in Biology Gordon Research Conference, Ventura, CA. .

Ahmed Elshewy, Michael Baldwin (11-03-2017. ) Formation of New Transition Metal Complexes Containing Two α-Hydroxy Acid Moieties .Ohio Inorganic Weekend, OSU, Columbus, OH. .

Mary Warmin, Michael Baldwin (11-03-2017. ) Effects of metal valence and size on the structure of siderophore-inspired complexes bearing alpha hydroxy acids .Ohio Inorganic Weekend, OSU, Columbus, OH. .

Ahmed Elshewy, Michael Baldwin (11-17-2017. ) Formation of New Transition Metal Complexes Containing Two α-Hydroxy Acid Moieties .Oesper Symposium/ACS Cincinnati Section Meeting, University of Cincinnati. .

Mary Warmin, Michael Baldwin (11-17-2017. ) Effects of metal valence and size on the structure of siderophore-inspired complexes .Oesper Symposium/ACS Cincinnati Section Meeting, University of Cincinnati. .

Michael J. Baldwin (01-2018. ) Bioinspired, alpha-hydroxy acid-containing chelates for photochemical control of transition metal chemistry .Metals in Biology Gordon Research Conference, Ventura, CA. . Conference. . Level:International

Ahmed Elshewy, Michael Baldwin (11-09-2018. ) Formation of New Transition Metal Complexes Containing Two α-Hydroxy Acid Moieties .Oesper Symposium, Cincinnati, OH. . Professional Meeting. . Level:Local

Mary Warmin,Brynn Leach, Michael Baldwin (11-09-2018. ) Light-activated ROS generation by a nano-encapsulated iron complex .Oespeer Symposium, Cincinnati, OH. . Professional Meeting. . Level:Local

Michael Baldwin (01-27-2019. ) A Bio-inpired Iron Complex for Photodynamic Therapy .Gordon Research Conference, Ventura, CA. . Conference. . Level:International

Michael J. Baldwin (01-20-2020. ) Bio-inspired chelates with two distinct metal binding sites and their homometallic and heterometallic complexes .Gordon Research Conference, Ventura, CA. . Level:International

Benjamin Crabtree and Michal J. Baldwin (10-22-2021. ) Divalent and trivalent metal complexes of alpha-hydroxy acid-containing chelates and their photoactive properties .Oesper Symposium, University of Cincinnati. . UC. . Level:Local

Mary R. Warmin, Dominic J. DuPonty and Michael J. Baldwin (10-22-2021. ) Structure, stabilityand metal exchange of an Al(III) complex bearing alpha-hydroxy acids .Oesper Symposium, University of Cincinnati. . UC. . Level:Local

Ben Crabtree, Michael Baldwin (10-14-2022. ) Divalent and trivalent metal complexes of -hydroxy acid and amide-containing chelates and their photoactive properties .Oesper Symposium/Cincinnati ACS Poster Session, Cincinnati, OH. . Level:Local

Mary R. Warmin, Dominick Duponty, Jeanette A. Krause and Michael J. Baldwin (01-22-2023. ) Comparison of M(III) (M = Fe, Al, Ga, In) complexes of siderophore-inspired, alpha-hydroxy acid-containing chelates .Gordon Research Conference, Ventura, CA. . Conference. .

Paper Presentations

(04-10-2002. ) Characterization and reactivity of oxygen-active Ni(II) oximate complexes .Orlando, FL.

Mark Shelton (10-29-2011. ) Novel Light Responsive alpha-Hydroxy Acid Iron Chelates .Cincinnati, OH. UC.

Event Organized

Approaches to Bioinorganic Chemistry Symposium 05-17-2000 2000 Central Regional Meeting of the American Chemical Society, Covington, KY

4th Annual Ohio Inorganic Weekend 11-21-2003 11-22-2003 University of Cincinnati

Bioinorganic Chemistry Symposium 05-22-2007 2007 Central Regional Meeting of the American Chemical Society, Covington, KY

(Graduate Program Director ) Type:Departmental Service 09-2007 -09-2021

(Inorganic Division ) Committee Chair Type:Departmental Service 09-2003 -To Present

(A&S Graduate Council ) Member Type:University/College Service 09-2007 -12-2021

(University Graduate Council - A&S representative ) Member Type:University/College Service 09-2007 -04-2016

The Graduate School (New Programs Committee ) Member Type:University/College Service 09-2014 -04-2016

(Graduate Curriculum and Appointments Committee ) Committee Chair Type:Departmental Service

(Graduate School Summer Programs ) Director Type:University/College Service 05-2010 -09-2013

(A&S Graduate Council ) Committee Chair Type:University/College Service 08-2012 -08-2013

(University Graduate Council ) Member Type:University/College Service 08-2013 -04-2017

College of Arts and Sciences (Grievance Committee ) Committee Member Type:University/College Service Level:College 09-01-2015 -10-16-2015

(RPT Committee ) Member Level:Department

(Education Strategy Committee ) Member Type:Departmental Service Level:Department

(Pharmacy Ph.D. Program Review ) Reviewer Type:University/College Service

(Academic Program Review Committee ) Member Type:University/College Service 09-2018 -04-2020

Sycamore High School Chemistry Club Type:Other Educational Service Level:Local

(A&S Dean's 21st Century Task Force ) Committee Member Type:University/College Service 09-2020 -04-2021

(Grievance Committee ) Committee Member Type:University/College Service 09-20-2023 -10-31-2023

(Assistant Department Head ) Other Type:Departmental Service 08-01-2022 -12-31-2023

Department Head Type:Departmental Service 01-01-2024

06-1992-05-1997 Postdoctoral Fellow, University Of Michigan, , Ann Arbor, MI

biological, environmental, organic, photochemistry

Member, Sigma Xi

Member, American Chemical Society

15-CHEM-442 INORGANIC CHEM II Level:Undergraduate

15-CHEM-106 GOBCHEM III Level:Undergraduate

Physical Methods in Inorganic Chemistry Level:Graduate

15-CHEM-104 GOBCHEM I Level:Undergraduate

15-CHEM-753 SEL TOP INORG CHEM Bioinorganic Chemistry Level:Graduate

15-CHEM-442 INORGANIC CHEM II Level:Undergraduate

Physical Methods in Inorganic Chemistry Level:Graduate

Modern Spectroscopy Level:Graduate

Scientific Writing Level:Graduate

Electronic Structure and Spectroscopy of Transition Metal Compounds Level:Graduate

Bioinorganic Chemistry Level:Graduate

Modern Spectroscopy Level:Graduate

Modern Spectroscopy Level:Graduate

Scientific Writing for Chemists Level:Graduate

Modern Spectroscopy Level:Graduate

Scientific Writing for Chemists Level:Graduate

Bioiinorganic Chemistry Level:Graduate

Electronic Structure and Spectroscopy of Transition Metal Compounds Level:Graduate

-CHEM-1040 GEN CHEM I Level:Undergraduate

-CHEM-4020 INORG CHEM LECTURE Level:Undergraduate

Bioinorganic Chemistry Level:Graduate

-CHEM-1040 GEN CHEM I Level:Undergraduate

Scientific Writing for Chemists Level:Graduate

-CHEM-1040 GEN CHEM I Level:Undergraduate

-CHEM-4020 INORG CHEM LECTURE Level:Undergraduate

-CHEM-2031L SURVEY BIOCH LAB II Level:Undergraduate

-CHEM-1030 GEN/ORG/BIO CHEM I Level:Undergraduate

-CHEM-1040 GEN CHEM I Level:Undergraduate

-CHEM-2031L SURVEY BIOCH LAB II Level:Undergraduate

-CHEM-1030 GEN/ORG/BIO CHEM I Level:Undergraduate

Modern Spectroscopy Level:Graduate

BAD DATE -BAD DATE Assessment Plans CETL UC Type:Workshop

Faculty Development Lunch Discussions, Chemistry Department Type:Other